Stereoselective approach to the dihydroagarofuran framework via directed intramolecular radical addition
β Scribed by James D. White; Hyunik Shin
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 170 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The radical derived from bromvaceta112 undergoes intramolecular addition to give predominantly the cyclic acetal 13 in which the C12 methyl substituent is endo.
π SIMILAR VOLUMES
New convenient and stereoselective route to linear isoprenoids including the construction of Z-trisubstituted double bond is elaborated based on directed aldol condensation. We have previously reported' that the directed aldol condensation2 of dlitbated aldimines J\_ with aldehydes 1 is highly ster
## Abstract The photoaddition **6**β**7**, followed by a reductive cleavage of the ββchlorocyclobutylketone **7**, gave the stereochemically pure spiro [4,5]decane **8**.