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Stereoselective and Efficient Total Synthesis of Optically Active Tetrodotoxin from d -Glucose

✍ Scribed by Sato, Ken-ichi; Akai, Shoji; Shoji, Hirotsugu; Sugita, Naoki; Yoshida, Shiho; Nagai, Yoshinao; Suzuki, Katsuhiko; Nakamura, Yutaka; Kajihara, Yasuhiro; Funabashi, Masuo; Yoshimura, Juji

Book ID
125537356
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
229 KB
Volume
73
Category
Article
ISSN
0022-3263

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Stereoselective total synthesis of (+)-l
Stereoselective total synthesis of (+)-lactacystin from d-glucose
✍ Noritaka Chida; Jun Takeoka; Kohji Ando; Noriko Tsutsumi; Seiichiro Ogawa πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 776 KB

The chiral and stereoselective synthesis of (+)-lactacystin 1, the first non-protein neurotrophic factor having an ct,~t-disubstituted a-amino acid structure, is described. The highly functionalized y-lactam portion possessing a tetra-substituted carbon with nitrogen in I was effectively constructed