Stereoselective Alkene Synthesis

✍ Scribed by Mitsuru Shindo, Kenji Matsumoto (auth.), Jianbo Wang (eds.)

• Publisher: Springer-Verlag Berlin Heidelberg
• Year: 2012
• Tongue: English
• Leaves: 282
• Series: Topics in Current Chemistry 327
• Edition: 1
• Category: Library

✦ Synopsis

Stereoselective Synthesis of Tetrasubstituted Alkenes via Torquoselectivity-Controlled Olefination of Carbonyl Compounds with Ynolates, by Mitsuru Shindo and Kenji Matsumoto.- Stereoselective Synthesis of Z-Alkenes, by Woon-Yew Siau, Yao Zhang and Yu Zhao.- Stereoselective Synthesis of Mono-fluoroalkenes, by Shoji Hara.- Recent Advances in Stereoselective Synthesis of 1,3-Dienes, by Michael De Paolis, Isabelle Chataigner and Jacques Maddaluno.- Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents, by Yang Hu and X. Peter Zhang.- Selective Alkene Metathesis in the Total Synthesis of Complex Natural Product, by Xiaoguang Lei and Houhua Li.- Olefination Reactions of Phosphorus-Stabilized Carbon Nucleophiles, by Yonghong Gu and Shi-Kai Tian.- Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones, by Yan Zhang and Jianbo Wang.

✦ Table of Contents

Front Matter....Pages i-vii
Stereoselective Synthesis of Tetrasubstituted Alkenes via Torquoselectivity-Controlled Olefination of Carbonyl Compounds with Ynolates....Pages 1-32
Stereoselective Synthesis of Z -Alkenes....Pages 33-58
Stereoselective Synthesis of Mono-fluoroalkenes....Pages 59-86
Recent Advances in Stereoselective Synthesis of 1,3-Dienes....Pages 87-146
Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents....Pages 147-162
Selective Alkene Metathesis in the Total Synthesis of Complex Natural Product....Pages 163-196
Olefination Reactions of Phosphorus-Stabilized Carbon Nucleophiles....Pages 197-238
Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N -Tosylhydrazones....Pages 239-269
Back Matter....Pages 271-275

✦ Subjects

Organic Chemistry; Catalysis; Industrial Chemistry/Chemical Engineering