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Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid

✍ Scribed by Wonwoo Nam; Ju Yeon Ryu; Inwoo Kim; Cheal Kim

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 191 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01060-2

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✦ Synopsis

Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO 4 ) 2 >Mn(ClO 4 ) 2 >Fe(ClO 4 ) 2 .

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✍ Georgiy B Shul’pin; Helen Stoeckli-Evans; Dalmo Mandelli; Yuriy N Kozlov; Ana Te 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 187 KB

Tetradentate amine N,N -bis(2-pyridylmethylene)-1,4-diaminodiphenyl ether (compound 1) dramatically accelerates the oxidation of alkanes with MCPBA in acetonitrile catalyzed by FeCl 3 , whereas N,N -bis(2-pyrrolidinmethylene)-1,4-diaminodiphenyl ether (2) does not affect the reaction. The selectivit