Silylated vinyloxiranes 1, substituted on the double bond, have been synthesized and reacted under very mild conditions in the presence of a catalytic amount of palladium (0). They rearrange into txsilylated-13,7-unsaturated aldehydes 2, not only with complete chirality transfer but also with total
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Stereoselective addition of nucleophiles on α-trialkylsilyl-β,γ-unsaturated aldehydes
✍ Scribed by Franck Le Bideau; Fabienne Gilloir; Ylva Nilsson; Corinne Aubert; Max Malacria
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 179 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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