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Stereoselection in Reactions of Chiral Allyl Ethers: The Case of 1,3-Dipolar Cycloaddition
✍ Scribed by Laura Raimondi; Maurizio Benaglia
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 681 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
The 1,3-dipolar cycloaddition of formaldehyde N-electrostatic interactions in the reaction TS. The force field approach previously developed for evaluating the benzylnitrone with βЈ-alkoxyand γ-alkoxy-α,β-unsaturated esters was investigated. The stereochemical outcome of stereoselection in nitrile o
## Abstract magnified image Regio‐ and stereoselective 1,3‐dipolar cycloaddition of nitrile oxides to internal 2‐pentenols, α,β‐unsaturated esters and amides catalyzed by __R__‐(+) BINOL‐lanthanide complexes affords corresponding 3‐aryl‐2‐isoxazolines with enantioselectivities up to 89% ee.