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Stereopopulation control. I. Rate enhancement in the lactonizations of o-hydroxyhydrocinnamic acids

✍ Scribed by Milstien, Sheldon; Cohen, Louis A.


Book ID
120055002
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
966 KB
Volume
94
Category
Article
ISSN
0002-7863

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Phthalic anhydride was detected spectrophotometrically in the hydrolysis of o-carboxybenzohydroxamic acid (OCBA) in CH 3 CN-H 2 O solvent containing 0.03 mol dm Γ€3 HCl. Pseudo-first-order rate constants (k 1 ) for hydrolysis of OCBA are almost independent of the change in CH 3 CN content from 10 to