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Stereoisomere 2.5-Dimethyl-2.3:4.5-dioxydohexane als Hauptprodukte bei der Pyrolyse von polymerem 2.5-Dimethyl-2.4-hexadienperoxyd

✍ Scribed by Dr. G. Bernhardt; Prof. Dr. F. Korte


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
227 KB
Volume
77
Category
Article
ISSN
0044-8249

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Stereoisomeric 2,5-Dimethyl-2,3:4,5-diox
✍ Dr. G. Bernhardt; Prof. Dr. F. Korte 📂 Article 📅 1965 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB

The [Co(PF3)4]0 anion can be precipitated from aqueous solutions with voluminous cations. During the conversion of HCo(PF3)d into [Co(PF3)4]0, a bathochroniic shift of the P-F valence vibrations is observed which is probably due to a reduction in the double-bond character of the P-F bond. At PF3-pr