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Stereogradient Polymers Formed by Controlled/Living Radical Polymerization of Bulky Methacrylate Monomers

✍ Scribed by Kenji Ishitake; Kotaro Satoh; Masami Kamigaito; Yoshio Okamoto

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
482 KB
Volume
121
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Unter Kontrolle: Das sperrige Monomer Triphenylmethylmethacrylat (TrMA) wurde mithilfe von RAFT‐Reagentien polymerisiert (RAFT: reversibler Additions‐Fragmentierungs‐Kettentransfer). Stereogradiente Polymere, in denen die Isospezifität mit Abnahme der Monomerkonzentration spontan zunahm, entstanden in einem Polymerisations‐Depolymerisations‐Gleichgewicht, durch das ein weniger stabiles wachsendes Polymerende in eine stabilere Form überführt wird (siehe Bild).magnified image

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Semiconductor-polymer hybrids prepared by incorporating polymer brushes on semiconductor substrates have attracted considerable attention in recent years. The hybrids have unique surface and interface properties, [1][2][3][4][5][6][7][8][9][10] and allow the fabrication of nanopatterns. [11][12][13]