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Stereoelectronic Effects on 1 H Nuclear Magnetic Resonance Chemical Shifts in Methoxybenzenes

✍ Scribed by Lambert, Maja; Olsen, Lars; Jaroszewski, Jerzy W.

Book ID
127343250
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
339 KB
Volume
71
Category
Article
ISSN
0022-3263

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The "C NMR spectra of 21 catechin derivatives substituted at C-6/C-S by bromine and/or hydrogen and at oxygen by methyl, acetyl and/or hydrogen have been analysed in deuteriated acetone and chloroform. When a methoxy group is flanked by two bulky orrho substituents (6-Br and C4), the M e 0 and ortho