Stereoelectronic Effects in α-Carbanions of Conformationally Constrained Sulfides, Sulfoxides, and Sulfones

Stereoelectronic Effects in Cyclic Sulfo

Stereoelectronic Effects in Cyclic Sulfoxides, Sulfones, and Sulfilimines: Application of the Perlin Effect to Conformational Analysis

✍ Tobias Wedel; Monika Müller; Joachim Podlech; Helmut Goesmann; Claus Feldmann 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 215 KB 👁 1 views

## Abstract The ^1^__J__~CH~ coupling constants in conformationally constrained sulfoxides, bissulfoxides, sulfoxide‐sulfones, and sulfilimines derived from 2‐benzylidene‐1,3‐dithiane and 2‐(2,2‐dimethylpropylidene)‐1,3‐dithiolane were measured by means of HMQC and HSQC NMR experiments and the Per