𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereoelectronic controlling features of allylic asymmetry. Application to ester enolate alkylations

✍ Scribed by McGarvey, Glenn J.; Williams, J. Michael


Book ID
127295479
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
376 KB
Volume
107
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


anti-Selective Aldol Reactions of Amino
✍ Grandel, Roland ;Kazmaier, Uli ;Nuber, Bernhard πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 842 KB

## Abstract Deprotonation of __N__‐protected esters of the amino acids alanine 1, ethylglycin 6, valine 7, and phenylalanine 8 with LDA and subsequent addition of various metal salts result in the formation of a probably chelated metal enolate. Aldol reactions of these enolates with aldehydes affor

Regio- and stereoselective palladium(0)-
✍ Maryse Rychlet Elliott; Anne-Lise Dhimane; Max Malacria πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 230 KB

Recently, we reported an efficient palladium(0) catalyzed allylation of a non-stabilized nucleophile, lithium enolate of ethyl isobutyrate 2a, with monoepoxide of isoprene la, as a first step in the total synthesis of epiilludol (scheme 1).] The synthetic value of the regio-and stereoselective allyl