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Stereoelectronic control of the rate of ring opening in azidofurans

✍ Scribed by Peter J. Newcombe; Robert K. Norris

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
112 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

swnmary . 5-Aside-2-fury1 alkyl ketones are converted into nitrogen and 4,5-dioxo-2-alkenenitriles in a reaction whose facility depends on the nature of the alkyl group.

The recent report of thermally induced fragmentation of asidoisoxasoles* prompts us to report a facile, but substituent dependent ring-opening reaction in some asidofurans.

The asides (A) and

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