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Stereoelective polymerization of d,l-lactide using N-heterocyclic carbene based compounds

โœ Scribed by Jensen, Tryg R.; Breyfogle, Laurie E.; Hillmyer, Marc A.; Tolman, William B.


Book ID
120359657
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
289 KB
Volume
21
Category
Article
ISSN
1359-7345

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Highly stereoelective polymerization of
โœ Nicolas Spassky; Muriel Wisniewski; Christian Pluta; Alain Le Borgne ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 564 KB

## Abstract A chiral Schiff's base/aluminium alkoxide initiator bearing a ligand derived from __R__โ€(+)โ€1,1โ€ฒโ€binaphthylโ€2,2โ€ฒโ€diamine was synthesized and used for the stereoelective polymerization of __rac__โ€(D,L)โ€lactide. Rather high stereoelectivity is observed: a polymer with 88% enantiomeric enr