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Stereodivergent Syntheses of ( Z )- and ( E )-Alkenylsilanes via Hydrosilylation of Terminal Alkynes Catalyzed by Rhodium(I) Iodide Complexes and Application to Silicon-Containing Polymer Syntheses

✍ Scribed by Mori, Atsunori; Takahisa, Eisuke; Yamamura, Yuichi; Kato, Tsuyoshi; Mudalige, Anoma P.; Kajiro, Hiroshi; Hirabayashi, Kazunori; Nishihara, Yasushi; Hiyama, Tamejiro

Book ID: 120358212
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 145 KB
Volume: 23
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om049922r

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Stereodivergent hydrosilylation of 1-alk

Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis

✍ Atsunori Mori; Eisuke Takahisa; Hiroshi Kajiro; Yasushi Nishihara; Tamejiro Hiya 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 50 KB

Hydrosilylation of 1-alkynes catalyzed by RhI(PPh 3 ) 3 gives (E)-and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-