## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Stereocontrolled synthesis of tropanol derivatives via palladium -catalyzed reactions
✍ Scribed by J.E. Bäckvall; Z.D. Renko; S.E. Byström
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 213 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A general method for the transformation of 1,3-cycloheptadienes to tropane alkaloid derivatives was developed. The procedure was applied to the stereocontrolled synthesis of the exe-and endo-tropanol derivatives 1 and 2. The approach is based on
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Abltract: Reaction of (±)-methyl 2-arylcyclohexenyl carbonate with tosyl amide in the presence of a catalytic amount ot Pd.,dba.CHCl 3 and (S)-BINAPO produced 2-aryleyciohexenyl tosyl amide with a high ee along with the starting material with a high ee. The reaction involved two processes, and (+)-a