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Stereocontrolled synthesis of 6-epi-D-purpurosamine B by iodocyclocarbamation of a chiral Z-olefin derived from L-alanine and L-malic acid

✍ Scribed by Keiji Kamiyama; Yasuharu Urano; Susumu Kobayashi; Masaji Ohno


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
269 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


6-epi-D-Purpurosamine B was synthesized efficiently through a chiral Z-olefin 8 derived from L-alanine and L-malic acid under complete stereochemical control by using iodocyclocarbamation as the key reaction.