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Stereocontrolled syntheses of fluorinated synthons and their application to the preparation of fluorinated sugars

✍ Scribed by K. Araki; J.S. Plummer; F. Gyenes; J. O'Toole; J.T. Welch

Book ID: 104150434
Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 37 KB
Volume: 54
Category: Article
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)83707-0

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✦ Synopsis

An improved, high yield procedure for the ester enolate Claisen rearrangement of 2-butenyl fluoroacetate to form stereoselectively 2-fluoro-3-methylpent-4-enoic-y acid (1) will be reported. The conversion of the acids (1) to 2-fluoro-3-methyl-r

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