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Stereocontrolled reduction of an oxazepinohexahydroindolo[2,3-a]quinolizine derivative: asymmetric total synthesis of (+)-tacamonine

✍ Scribed by Bruno Danieli; Giordano Lesma; Daniele Passarella; Alessandro Sacchetti; Alessandra Silvani

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 129 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01488-5

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✦ Synopsis

Efficient, stereocontrolled total synthesis of the title compound is described, starting from enantiopure intermediates. A key step was the diastereoselective catalytic hydrogenation of a pentacyclic oxazepinohexahydroindolo[2,3-a]quinolizine derivative.

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