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Stereocontrolled Reactions Mediated by Remote Sulfoxides: Formation and Reactivity of Enantiomerically Pure Benzylic Centers

✍ Scribed by Garcia Ruano Jose Luis Garcia Ruano Jose Luis; Ana M. Martin Castro

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Stereocontrolled reactions mediated by r
Stereocontrolled reactions mediated by remote sulfoxides: Formation and reactivity of enantiomerically pure benzylic centers
✍ José Luis García Ruano; Ana M. Martín Castro 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 704 KB

## Abstract Reactions of different electrophiles (alkyl halides, aldehydes, __N__‐sulfinylimines, imines, etc) with (__S__)‐2‐__p__‐toluenesulfinyl toluene and their alkyl, triisopropylsilyloxy, and methylthio derivatives at benzylic position, in the presence of LDA, allow the synthesis of a variet