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Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. Studies Directed Towards the Synthesis of Ebelactone A

✍ Scribed by Sarah C. Archibald; David J. Barden; Jerome F. Y. Bazin; Ian Fleming; Colin F. Foster; Ajay K. Mandal; Amit K. Mandal; David Parker; Ken Takaki; Anne C. Ware; et al. et al.

Publisher
John Wiley and Sons
Year
2004
Weight
17 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Formal Synthesis of (Β±)-Thienamycin. -The precursor (IX) of the title antibiotic is prepared from aldol product (Ib), which has a silyl group in the side chain as hydroxy surrogate. The trans disposed substituents at the azeti