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Stereocontrol in intramolecular hydrosilylation of allyl and homoallyl alcohols: a new approach to the stereoselective synthesis of 1,3-diol skeletons

โœ Scribed by Tamao, Kohei.; Nakajima, Takashi.; Sumiya, Ritsuo.; Arai, Hitoshi.; Higuchi, Noriko.; Ito, Yoshihiko.


Book ID
126933385
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
497 KB
Volume
108
Category
Article
ISSN
0002-7863

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Silafunctional compounds in organic synt
โœ Kohei Tamao; Tetsu Tanaka; Takashi Nakajima; Ritsuo Sumiya; Hitoshi Arai; Yoshih ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

Intramolecular hydrosilation of ally1 and homoallyl alcohols and the subsequent oxidative cleavage of the resultant carbon-silicon bond have provided a new approach to the regio-controlled synthesis of 1,2-and/or 1,3-diols. We have recently developed a new methodology for the anti-Markownikoff hydra