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Stereochemistry of vinyl polymers and NMR characterization

✍ Scribed by H. N. Cheng

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
578 KB
Volume
36
Category
Article
ISSN
0021-8995

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✦ Synopsis

The configuration of vinyl polymers has been conventionally described by either Bovey's or Price's formalism. In this work, the relationships between these two formalisms are derived, and their relevance to polymerization mechanisms is delineated. Experimental data for nuclear magnetic resonance (NMR) pertaining to either chain-end control or catalytic-site control are tested using the computerized "analytical approach." Suitable polymeric systems are illustrated.

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