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Stereochemistry of transition-metal-catalyzed cross-coupling reactions

โœ Scribed by Walborsky, H. M.; Banks, R. Bruce


Book ID
120928209
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
598 KB
Volume
46
Category
Article
ISSN
0022-3263

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The stereochemical course of Ni-and Pd-catalyzed reactions of t+)(S)-1 with isobutylmetal reagents has been elucidated by preparing the allene (+)-2 via an anti stereoselective transformation of the propargylic acetate c+)(R)-4 with organocuprates.