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Stereochemistry of the Robinson-Schoepf reaction. A stereospecific total synthesis of the ladybug defense alkaloids precoccinelline and coccinelline

โœ Scribed by Stevens, Robert V.; Lee, Albert W. M.


Book ID
111686756
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
480 KB
Volume
101
Category
Article
ISSN
0002-7863

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## Application of a Stereospecific Intramolecular Allenylsilane Imino Ene Reaction to Enantioselective Total Synthesis of the 5,11-Methanomorphanthridine Class of Amaryllidaceae Alkaloids. -Starting from the enantiomerically pure epoxy alcohol (I) the allenylsilane aldehyde (II) is prepared. Its