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Stereochemistry of the reactions of molecular oxygen with 1,4-dimethylcyclohexyl and 2-methylnorbornyl radicals generated from isomeric sources

โœ Scribed by Schindel, Wesley G.; Pincock, Richard E.


Book ID
120015458
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
897 KB
Volume
35
Category
Article
ISSN
0022-3263

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Kinetics of the reactions of 2,4,6-tri-t
โœ A. P. Griva; E. T. Denisov ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 318 KB

Reactions of 2,4,6-tri-t-butylphenoxyl (TBP) with cumene hydroperoxide (ROOH), cumylperoxyl radicals (RO,), and molecular oxygen in benzene solution have been investigated kinetically by the ESR method. The rate constant of the reaction TBP + ROOH -% TBPH + RO2 has been estimated in the temperature