Stereochemistry of the oxidative addition of optically active 8-(α-bromoethyl)quinoline to tris (triphenylphosphine)platinum

Influence of enolate geometry and struct

Influence of enolate geometry and structure on the stereochemistry of the asymmetric oxidation of prochiral ketone enolates to optically active α-hydroxy ketones

✍ Franklin A. Davis; Aurelia C. Sheppard; G.Sankar Lal 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 309 KB

The sfereoselectiviry for the asymmetric oxidation of enolafes to opfica//y active a-hydroxy ketones using (+)-( camphoryisulfonyi)oxaziridine is dependent on the enoiate substitution pattern, the solution structure of the enoiate and to a lesser extent the enoiate geometry Optically active a-hydrox