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Stereochemistry of the Michael addition. An interesting solvent effect

✍ Scribed by R.A. Abramovitch; D.L. Struble


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
234 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis


The Michael Addition has usually been studied under conditions such and J. M. Muchowski. Can. J Chem 3f& 557 (1960). U A* No.3 2. Correct analyzes were obtained for all the new compounds mentioned here. Reaction mixtures were analyzed quantitatively and qualitatively by gas-liquid chromatography.


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The Role of Noninnocent Solvent Molecule
✍ Mahendra P. Patil; Raghavan B. Sunoj 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 451 KB 👁 1 views

## Abstract A proline‐catalyzed asymmetric Michael addition between ketones and __trans__‐β‐nitrostyrene was studied by using the density‐functional theory with mPW1PW91 and B3LYP functionals. Improved insight into the enantio‐ and diastereoselective formation of γ‐nitroketones/‐aldehydes is obtain