Reductive cleavage of the external(a.8) bond of the cyclopropane ring in tricyclo[x.y.O.O \*,x9\_ alkan-3-ones with lithium in liquid ammonia provides a general method of synthesis of spirocyclic ketones. \*,3 Piers and Worster have recognized that the stereochemical fate of the S carbon atom is an
โฆ LIBER โฆ
Stereochemistry of the lithium-ammonia reduction of cis-1,7-dimethyltricyclo[4.4.0.02,6]decan-3-one and related compounds
โ Scribed by Piers, Edward; Worster, Paul M.
- Book ID
- 126998586
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 367 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
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