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Stereochemistry of the Conversions of l-Threonine and d-Threonine into 2-Oxobutanoate by the l-Threonine and d-Threonine Dehydratases of Serratia marcescens

✍ Scribed by David H. G. CROUT; Maria V. M. GREGORIO; Urs S. MÜLLER; Saburo KOMATSUBARA; Masahiko KISUMI; Ichiro CHIBATA


Book ID
115119357
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
819 KB
Volume
106
Category
Article
ISSN
1432-1327

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N-Acetylated threonine derivatives, having tert-butyl or benzyl-based side-chain protection, form isolable 5(4H)-oxazolones on treatment with N-ethyl-N'-3-dimetlaylaminopropyl carbodiimide. N-chloroacetylated threonine derivatives, on the other hand, do not form oxazolones so readily. The N-acetylat