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Stereochemistry of the conversion of cis- and trans-2-amino-1,3-dihydro-1,3-diphenylisoindoles into the corresponding 1,2-diphenylbenzocyclobutenes

✍ Scribed by Carpino, Louis A.


Book ID
121743278
Publisher
Royal Society of Chemistry
Year
1966
Weight
201 KB
Volume
15
Category
Article
ISSN
0009-241X

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Stereochemistry of the rearrangement of
✍ Elliot N. Marvell; William Whalley πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 178 KB

Rearrangement of 1,2-divinyl-1,2-cyclohexanediol (I) was shown by Coda, et al (1) to give l-bicyclo[5.3.O]decen-2-one (II). We had made the ssme observation independently (2), but had also found that under milder conditions 7-hydroxybicyclo[5.3,0] decsn-2-one (III) can be isolated in good yield. In