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Stereochemistry of the anomers of methyl 2-deoxy-D-erythro-pentofuranoside. Synthesis of methyl 5-(6-aminopurin-9yl)-2,5-dideoxy-.alpha.- D-erythro-pentofuranoside, a reversed nucleoside

✍ Scribed by Leonard, Nelson J.; Sciavolino, Frank C.; Nair, Vasudewan


Book ID
126051800
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
958 KB
Volume
33
Category
Article
ISSN
0022-3263

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Glycosidation of N-acetylneuraminic acid by phase-transfer catalysis in chloroform-aqueous alkali gave several known and some new aryl cY-ketosides in a short reaction time and in good yields. The 4-methylumbelliferyl cu-ketoside, the standard substrate for neuraminidase, was prepared in a yield of