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Stereochemistry of rings. x. lactone derivatives: Part 6. The structure of 5-hydroxy-2(3H)benzofuranone

✍ Scribed by Gabriele Bocelli; Marie-Florence Grenier-Loustalot


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
395 KB
Volume
82
Category
Article
ISSN
0022-2860

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Conformational analysis of benzoanellate
✍ Barbara Rys; Helmut Duddeck; Monika Hiegemann πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 450 KB

The NW? spectra of compounds l-5, recorded at different temperatures, are discussed and interpreted in terms of conformational eguilibrium. Ground state conformations are found to be chiral, ring inversion barriers are surprisingly high (ca 48 kJ/mol).