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Stereochemistry of retro-diel-salder fragmentation in gas-phase ions formed by chemical ionization

✍ Scribed by Shmuel Zitrin; Jehuda Yinon; Asher Mandelbaum


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
293 KB
Volume
34
Category
Article
ISSN
0040-4020

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Ion–molecule reactions in the gas phase.
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Under chemical ionization (CI) conditions, cis and trans 1,2-indanediols mainly react with the NH 3 /NH 4 + system via a nucleophilic substitution process. In the CI source several mechanisms can occur yielding the substituted [M + NH 4 -H 2 O] + ions at m/z 150. Collisionally activated reaction (CA