Stereochemistry of reduction of substituted cyclohexanones with lithium triisobutyl-n-butylaluminate
โ Scribed by Ashby, E. C.; Heinsohn, George E.
- Book ID
- 127146320
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 323 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Enantioselective deprotonation of 4-substituted cyclohexanones (1) in the presence of excess trimethylsilyl chloride was examined using chirai bidentate lithium amides ((R)-3~(R)-7) in THF. The solution structures of (R)-3a in THF in the presence and in the absence of lithium chloride were studied b
## Stereochemistry of Enantioselective Deprotonation of 4-Substituted Cyclohexanones by Chiral Bidentate Lithium Amides. -Enantioselective deprotonation of 4-substituted cyclohexanones using chiral lithium amide bases such as (I) in the presence of excess trimethylsilyl chloride results in format