Addition of dimethyl phosphonate to acetaldol gives a 3 : 7 mixture of diastereomeric dimethyl (1,3-dihydroxybutyl)phosphonates 3 and 4. The relative configurations at C-I and C-3 in these diols were established by the 13C NMR data of their 0-benzylidene derivatives. Axial preference-for the dimetho
✦ LIBER ✦
Stereochemistry of reactions in the 1,2-dimethylisilacyclopentane ring system
✍ Scribed by Frank K. Cartledge; Joanne M. Wolcott; Jacques Dubac; Pierre Mazerolles; Pierre Fagoaga
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 224 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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