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Stereochemistry of organophosphorus cyclic compounds—II : Stereospecific synthesis of cis- and trans 2-halogeno-2-oxo-4-methyl-1,3,2-dioxaphosphorinans and their chemical transformations

✍ Scribed by W. Stec; M. Mikołajczyk


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
752 KB
Volume
29
Category
Article
ISSN
0040-4020

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cis- and trans-2-(Isocyanomethyl)-5,5-di
✍ Jan-Willem Weener; Jos P. G. Versleijen; Auke Meetsma; Wolter ten Hoeve; Albert 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 320 KB 👁 1 views

Both cis-2-(isocyanomethyl)-5,5-dimethyl-2-oxo-4-phenyl-upon dehydration gave 1a. Thus, both (±)-1a and (2S,4S)-(Ϫ)-1a were prepared, and their molecular structures were 1,3,2-dioxaphosphorinane (1a) and the trans epimer 1b have been prepared as potentially useful chiral isocyano-determined by singl