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Stereochemistry of opening of cyclopropanols. trans-2,3-Di-tert-butylcyclopropanone hemiketals

✍ Scribed by Wharton, P. S.; Fritzberg, A. R.


Book ID
126993049
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
578 KB
Volume
37
Category
Article
ISSN
0022-3263

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flat region. The analysis of the theoretical results shows that the solvent reaction field decreases the energy barriers for the ring-opening processes and a stabilization of the oxyallyl intermediates takes place. The calculated relative barrier heights are in good agreement with the experimental d