Stereochemistry of nucleophilic additions to 2,3-endo, endo-bridged-7-ketonorbornanes [tricyclo(5.2.1.02,6)decan-10-ones]. Observation of long-range electronic effects

✍ Scribed by Goverdhan Mehta; Marapaka Praveen

• Book ID: 104224794
• Publisher: Elsevier Science
• Year: 1992
• Tongue: French
• Weight: 233 KB
• Volume: 33
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)91726-x

✦ Synopsis

The diastereoselectivities exhibited by sterically unbiased &-tricyclo(5.2.1.02,6)decan-lo-ones in nucleophilic additions can be modulated through substituents in the distal five membered ring.