𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereochemistry of Migrating Carbon In Wagner-Meerwein rearrangement

✍ Scribed by T. Shono; K. Fujita; S. Kumai


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
212 KB
Volume
14
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Mechanism of Wagner-Meerweln rearrangement 11 , especially the rearrangement of P-phenylethyl cation and norbonyl cation system, has been vastly studied on


📜 SIMILAR VOLUMES


The acid-catalyzed Wagner-Meerwein rearr
✍ John W. ApSimon; John A. Buccini; Alfred S.Y. Chau 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 163 KB

In acidic media, aldrin' and its dechloro-derivatives 3 undergo Wagner-Meerwein type rearrangements to form derivatives of isodrin: an analogous rearrangement of dieldrin has not yet been reported. ## Reaction of dieldrin with various acids is reported to give either 4-oxo-4,5-dihydroaldrin 485

1,2-Shift of a Carboxyl Group in a Wagne
✍ Daniel Berner; D. Philip Cox; Hans Dahn 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 535 KB

## Abstract On treatment with HSO~3~F in SO~2~C1F at 0°, 3‐hydroxy‐2,2‐dimethyl‐3‐phenyl‐propionic acid (**1a**) is transformed into 2‐phenyl‐3‐methyl‐2‐butenoic acid (**2a**) (isolated yield: 40–44%). Using monolabelled [3‐^13^C]‐**1a** (**1a**\*) and doubly labelled [1,3‐^13^C~2~]‐**1a** (**1a**\