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Stereochemistry of Macrocyclization of cis-4-Cyclohexene-1,2-dicarboxylic Acid with Dihalogen Derivatives.

✍ Scribed by A. L. Shabanov; M. M. Gasanova; Ch. I. Mamedov

Publisher: John Wiley and Sons
Year: 2003
Weight: 131 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200310172

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## Abstract A novel Lewis acid‐catalyzed [3+4] annulation of 2‐(heteroaryl)cyclopropane‐1,1‐dicarboxylates with cyclopentadiene is reported. This reaction proceeds __via__ an electrophilic attack of the Lewis acid‐activated donor‐acceptor cyclopropane onto cyclopentadiene followed by Friedel–Crafts