Stereochemistry of ion-pair return. Isomerization and racemization of p-chlorobenzhydryl thiocyanate in acetonitrile.

Ion pairs, racemization, chloride exchan

Ion pairs, racemization, chloride exchange and the mass law effect in solvolysis of p-chlorobenzhydryl chloride

✍ S. Winstein; Masaru Hojo; S. Smith 📂 Article 📅 1960 🏛 Elsevier Science 🌐 French ⚖ 437 KB

fn the classic lmestigations of C. K. Ingold and MS coworke~3~, solvolysis of benzbydryl type halides in aqueous acetone was interpreted with the sid of only Olle variety of C8fbOAiMil ion irIteI?x?diate, the ais-8OCi8ted cation, R 83 , at3 in equation (1). In the m-called me8 law effect ROK (canon