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Stereochemistry of ethynylation, normant, and grignard reactions in the 1-alkyldecahydro-4-quinolone series

โœ Scribed by A. A. Akhrem; L. I. Ukhova; G. P. Kukso; S. M. Volkov; N. I. Garbuz; L. P. Solovei

Book ID
112325259
Publisher
Springer US
Year
1976
Tongue
English
Weight
412 KB
Volume
12
Category
Article
ISSN
0009-3122

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๐Ÿ“œ SIMILAR VOLUMES

The stereochemistry of the Grignard โ€” Or
The stereochemistry of the Grignard โ€” Ortho ester reaction revisited: Regioselective endocyclic cleavage in the reaction of Grignard reagents with cis-2-methoxy-4-methyl-1,3-dioxane
โœ William F. Bailey; Allan A. Croteau; Alberto D. Rivera ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 304 KB

The reaction of cis-2-methoxy-4-methyl-1,3-dioxane (4) with Grignard reagents proceeds in a totally regioselective manner via rupture of the less congested C(2)-0(1) bond remote from the 4-methyl substituent. The analogous r-2-methoxy-cis-4,cis-6-dimethyi-l,3dioxane (2) is totally inert to the acti

ChemInform Abstract: The Stereochemistry
ChemInform Abstract: The Stereochemistry of the Grignard -Ortho Ester Reaction Revisited: Regioselective Endocyclic Cleavage in the Reaction of Grignard Reagents with cis-2-Methoxy-4-methyl-1,3-dioxane.
โœ W. F. BAILEY; A. A. CROTEAU; A. D. RIVERA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 2 views

The Stereochemistry of the Grignard -Ortho Ester Reaction Revisited: Regioselective Endocyclic Cleavage in the Reaction of Grignard Reagents with cis-2-Methoxy-4-methyl-1,3-dioxane. -cis-Dioxane (Ia) selectively reacts with Grignard reagents (cf. (II)) via rupture of the less congested C(2)-O(1) bo