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Stereochemistry of Diels-Alder reactions at high pressure. 4. Asymmetric induction in high-pressure cycloadditions of (R)-(-)-menthyl glyoxylate and symmetric 1,3-dienes

✍ Scribed by Jurczak, Janusz; Tkacz, Marek


Book ID
126257837
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
775 KB
Volume
44
Category
Article
ISSN
0022-3263

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Organic reactions at high pressure. Asym
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Asymmetric induction in the high pressure (15 kbar, 1.5 GPa) Duels-Alder reactlon of e-benzoqulnone with choral 2,4-pentadienoic acid derivatives is evaluated The reactions afford 4a,5,8,8a-tetrahydro-1,4-naphthalenedlones in up to 50% enantlomenc excess.