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Stereochemistry of cyclopropylcarbinyl rearrangements. Synthesis and solvolysis of cyclopropylcarbinyl-1,1',1'-trans-2,3,3-d6 methanesulfonate

โœ Scribed by Schleyer, Paul v. R.; Majerski, Zdenko


Book ID
126124135
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
856 KB
Volume
93
Category
Article
ISSN
0002-7863

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Stereochemistry of the 1,2-Wittig rearra
โœ Stuart L. Schreiber; Mark T. Goulet ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 259 KB

The [1,2] Wittig rearrangement of P-alkoxyalkyl ally1 ethers has been studied and found to provide syn-1,3-diol derivatives in 14-32% yield and with useful levels of diastereoselection. The rearrangement of a-metalated ethers (Wittig rearrangement) has been of interest to investigators since its di