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Stereochemistry of crotylboronate additions to .alpha.,.beta.-dialkoxy aldehydes

โœ Scribed by Roush, William R.; Adam, Michael A.; Harris, David J.


Book ID
126126008
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
504 KB
Volume
50
Category
Article
ISSN
0022-3263

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Stereoselective synthesis of alcohols, X
โœ Brinkmann, Heinrich ;Hoffmann, Reinhard W. ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 714 KB

Allylboration reaction / Asymmetric induction / Calculations, force-field / Transition-state models The direction (Cramlanti-Cram) and the extent of asymmetric induction on addition of crotylboronates to a range of chiral aldehydes was investigated. A reversal in the sense of the asymmetric inducti