Stereochemistry of Congested Cyclophanes Containing Chiral Spirobiindanol Phosphonates: Syntheses, X-Ray Structure, HPLC Enantioresolution and Clathration Properties
β Scribed by Giuseppe A. Consiglio; Paolo Finocchiaro; Salvatore Failla; Kenneth I. Hardcastle; Candace Ross; Salvatore Caccamese; Giuseppe Giudice
- Book ID
- 101280942
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 400 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-193X
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β¦ Synopsis
The synthesis as well as the stereochemical characterization preparation of our compounds proved to be very satisfactory and all cyclophanes were obtained in high yield (Υ 70%). (in solution) of sterically congested cyclophanes containing the chiral spirobiindanol phosphonate moiety is reported.
Only the [1+1] cyclization products were found to be significatively formed in the reaction. The Williamson's synthetic procedure used for the [a] Instituto Chimico Facolta Β΄di Ingegneria, Universita Β΄di Catania, contrast, when the 2,2-bis(3-diethylphosphono-4-hydroxy-V.le A. Doria, I-6-95125 Catania (IT)
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