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Stereochemistry of Congested Cyclophanes Containing Chiral Spirobiindanol Phosphonates: Syntheses, X-Ray Structure, HPLC Enantioresolution and Clathration Properties

✍ Scribed by Giuseppe A. Consiglio; Paolo Finocchiaro; Salvatore Failla; Kenneth I. Hardcastle; Candace Ross; Salvatore Caccamese; Giuseppe Giudice


Book ID
101280942
Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
400 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis


The synthesis as well as the stereochemical characterization preparation of our compounds proved to be very satisfactory and all cyclophanes were obtained in high yield (Υ† 70%). (in solution) of sterically congested cyclophanes containing the chiral spirobiindanol phosphonate moiety is reported.

Only the [1+1] cyclization products were found to be significatively formed in the reaction. The Williamson's synthetic procedure used for the [a] Instituto Chimico Facolta Β΄di Ingegneria, Universita Β΄di Catania, contrast, when the 2,2-bis(3-diethylphosphono-4-hydroxy-V.le A. Doria, I-6-95125 Catania (IT)


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ChemInform Abstract: Synthesis and X-Ray
✍ Giuseppe A. Consiglio; Salvatore Failla; Paolo Finocchiaro; Fabio Marchetti πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

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