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Stereochemistry of benzannelated 1,6-diazabicyclo[4.2.1]octadienes and the conformation of substituents on the methylene bridge

✍ Scribed by E. Kleinpeter; J. Hartmann; B. Werner; W. Schroth

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 276 KB
Volume: 28
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260280508

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✦ Synopsis

Abstract

The stereochemistry of benzannelated 1,6‐diazabicyclo[4.2.1]octa‐3,7‐dienes (the conformation of the eight‐membered ring and of the variable substituents on the methylene bridge) was determined by means of NOE enhancements and stereospecific long‐range H,H coupling constants in the relevant NMR spectra.

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