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Stereochemistry of anionic vinyl polymerization. Effects of ion pair prochirality on chain statistics

✍ Scribed by Mueller, A. H. E.; Hogen-Esch, T. E.

Book ID
126070310
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
450 KB
Volume
21
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Anionic polymerization of 2-vinylpyridin
Anionic polymerization of 2-vinylpyridine: a computational study of solvent effects on polymerization stereochemistry.
✍ Lawrence M. Pratt; Ishrat M. Khan; Thieo E. Hogen-Esch πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 621 KB

## Abstract Anionic polymerization of 2‐vinylpyridine shows significant solvent effects on the polymer stereochemistry. Polymerization with butyllithium in tetrahydrofuran (THF) yields a largely isotactic polymer, while polymerization with butyllithium in tetramethyl‐ethylenediamine (TMEDA) results