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Stereochemistry of allenes

✍ Scribed by DeVille, T. E.; Hursthouse, M. B.; Russell, S. W.; Weedon, B. C. L.

Book ID
120330309
Publisher
Royal Society of Chemistry
Year
1969
Weight
221 KB
Volume
13
Category
Article
ISSN
0577-6171

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An allene of appropriate substitution has four distinguishable attitudes of presentation to a solid catalyst (Ip-IVp) leading by 1,2-a-addition to four different olefins (I-IV). (Received in UK 30 June 1967) on approach of the oriented allene to the catalyst might be expected to be important whether